Season the Pork Chops: In a small bowl, mix chili powder, cumin, garlic powder, paprika, salt, and black pepper. Rub the seasoning evenly over both sides of the pork chops.
Sear the Pork Chops: Heat olive oil in a large skillet over medium-high heat. Sear the pork chops for 2-3 minutes per side until golden brown. Remove from the skillet and set aside.
Sauté the Vegetables: In the same skillet, add chopped onion, bell pepper, and garlic. Cook for 2-3 minutes until softened.
Toast the Rice: Stir in the uncooked rice and cook for 1 minute, stirring constantly.
Add Liquids & Simmer: Pour in the diced tomatoes with green chilies, chicken broth, black beans, and corn. Stir well, then place the pork chops back into the skillet on top of the rice.
Cook the Dish: Cover and simmer over medium-low heat for 20-25 minutes, or until the rice is tender and the pork reaches an internal temperature of 145°F (63°C).
Rest & Garnish: Remove from heat and let it sit for 5 minutes. Sprinkle with cheese and fresh cilantro. Serve with lime wedges for extra flavor.